Toughening of poly(butylene terephthalate) by addition of core-hell particles

ZHAO ChenYang1;LI ShaoYing1;WANG ChengZhong2

Journal of Beijing University of Chemical Technology ›› 2011, Vol. 38 ›› Issue (5) : 86-89.

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Journal of Beijing University of Chemical Technology ›› 2011, Vol. 38 ›› Issue (5) : 86-89.
材料科学与工程

Toughening of poly(butylene terephthalate) by addition of core-hell particles

  • ZHAO ChenYang1;LI ShaoYing1;WANG ChengZhong2
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Abstract

Core-shell polymer particles have been synthesized from methyl methacrylate (MMA) and butyl acrylate (BA). The mechanical properties of poly(butylene terephthalate) (PBT) were studied after addition of the core-shell particles and maleic anhydride-grafted polyethylene-octane (POE) copolymer as impact modifiers. The results showed that the PBT had the maximum toughness when the monomer ratio of MMA:BA in the core-shell polymer was 23. The particle size of the core-shell particles decreased as the amount of initiator increased, and as a result the tensile strength of PBT increased. Synergistic effects on the mechanical properties of PBT were observed by adding both core-shell particles and maleic anhydride-grafted POE (POE-g-MAH). When blended core-shell particles and POE-g-MAH were added to PBT, the impact strength of PBT increased significantly.

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ZHAO ChenYang1;LI ShaoYing1;WANG ChengZhong2
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Toughening of poly(butylene terephthalate) by addition of core-hell particles[J]. Journal of Beijing University of Chemical Technology, 2011, 38(5): 86-89

References

[1]王新波, 周正华. POE马来酸酐接枝物增韧PBT[J]. 合成技术及应用, 2002, 17(2):9-10.
Wang X B, Zhou Z H. Toughening for poly butylene terephthalate with polyetin elastomer grafted by maleic anhydride[J]. Synthetic Technology and Application, 2002, 17(2):9-10. (in Chinese)
[2]唐毓萍, 应敏, 张发饶. POE熔融接枝GMA的制备及其与PBT共混增韧[J]. 塑料, 2007, 36(4): 27-31. 
Tang Y P, Ying M, Zhang F R. Toughening of melt grafting of GMA onto POE and PBT[J]. Plastic, 2007, 36(4): 27-31. (in Chinese)
[3]董丽杰, 张会轩, 杨海东, 等. EPM-g-GMA接枝率的测定及其增韧PBT的力学性能和形态结构研究[J]. 高分子学报, 2003 (2): 167-171. 
Dong L J, Zhang H X, Yang H D, et al. Toughening of PBT by means of blending with graft copolymer EPM-g-GMA[J]. Acta Polymerrica Sinica, 2003 (2): 167-171. (in Chinese)
[4]魏刚, 彭娅, 黄锐. PBT/官能化聚烯烃弹性体共混体系的力学性能与相形态[J]. 塑料工业, 2005, 33(8): 15-18. 
Wei G , Peng Y, Huang R. Mechanical properties and morphology of PBT/functional polyolefin elastomer blend[J]. China Plastics Industry, 2005, 33(8): 15-18. (in Chinese)
[5]Sun S L, Tan Z Y, Zhang M Y, et al. Influence of the degree of grafting on the morphology and mechanical properties of blends of poly(butylene terephthalate) and glycidyl methaerylate grafted poly(ethylene-co-propylene)[J]. Polymer International, 2006, 55(8): 834-838. 
[6]洪月蓉, 张玲, 牛建华, 等. 弹性体修饰纳米SiO2粒子改性PBT[J]. 复合材料学报, 2009, 26(3): 55-59. 
Hong Y R, Zhang L, Niu J H, et al. PBT matrix composites with elastomer-modified nano-SiO2 particles[J]. Acta Materiae Compositae Sinica, 2009, 26(3): 55-59. (in Chinese)
[7]程晓华, 于德梅.核-壳聚合物粒子增韧改性工程塑料[J]. 化工新型材料, 2001, 29(5): 23-25. 
Cheng X H, Yu D M. Toughening of engineering plastics by core-shell composite particles[J]. New Chemical Materials, 2001, 29(5): 23-25. (in Chinese)
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