Preparation of photoreactive polystyrene particles by charge-stabilized dispersion polymerization

ZHANG Fen;MA YuHong;LIU LianYing;CAO Le;YANG WanTai

Journal of Beijing University of Chemical Technology ›› 2011, Vol. 38 ›› Issue (1) : 77-82.

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Journal of Beijing University of Chemical Technology ›› 2011, Vol. 38 ›› Issue (1) : 77-82.
材料科学与工程

Preparation of photoreactive polystyrene particles by charge-stabilized dispersion polymerization

  • ZHANG Fen;MA YuHong;LIU LianYing;CAO Le;YANG WanTai
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Abstract

Polystyrene (PS) microspheres with benzophenone groups on the surface have been produced by a twostep polymerization method using sodium styrenesulfonate-stabilized dispersion polymerization in a methanol-water mixed solvent. The effects on the particles of varying the addition time of the functional monomer 4-allyloxy-2-hydroxybenzophenone (BP-OH), and the polymerization time were studied. Under UV irradiation, the fluorescent monomer 7-methacryloyl4-methylcoumarin could undergo polymerization with the functional PS particles. Characterization of the particles was performed by field emission scanning electron microscopy (FESEM), Fourier transform infrared spectroscopy (FT-IR), UV-Visible spectros copy and fluorescence microscopy (FM). The results indicated that the resulting particles possessed photoreactivity.

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ZHANG Fen;MA YuHong;LIU LianYing;CAO Le;YANG WanTai. Preparation of photoreactive polystyrene particles by charge-stabilized dispersion polymerization[J]. Journal of Beijing University of Chemical Technology, 2011, 38(1): 77-82

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