Removal of thiophenic sulphide compounds from gasoline by condensation with a desulfurizing agent

WANG XingHua;ZHANG Jie;HUANG ChongPin

Journal of Beijing University of Chemical Technology ›› 2011, Vol. 38 ›› Issue (1) : 110-115.

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Journal of Beijing University of Chemical Technology ›› 2011, Vol. 38 ›› Issue (1) : 110-115.
生物技术与环境工程

Removal of thiophenic sulphide compounds from gasoline by condensation with a desulfurizing agent

  • WANG XingHua;ZHANG Jie;HUANG ChongPin
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Abstract

Thiophenic sulfur compounds can be effectively converted by condensation with CD-1 desulfurizing agent catalyzed by Amberlyst-15 acid porous resin. The thiophenes are transformed to compounds with a boiling temperature beyond the gasoline distillation range, and thus the sulfur compounds can conveniently be removed by distillation. The optimum reaction conditions for desulfurization of a model gasoline sample were found to be a temperature of 80℃ a reaction time of 20 minutes, condensation agent-to-oil mass ratio of 1:100, and catalyst-to-oil mass ratio of 1∶10, giving a conversion of thiophene of ~100%. Basic nitrogenous compounds in gasoline had an adverse effect on the catalyst. The condensation desulfurization methods exhibited high sulfur removal efficiency and has promising prospects for practical application. 

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WANG XingHua;ZHANG Jie;HUANG ChongPin. Removal of thiophenic sulphide compounds from gasoline by condensation with a desulfurizing agent[J]. Journal of Beijing University of Chemical Technology, 2011, 38(1): 110-115

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