
Monodispersed cationic microspheres of polystyrene prepared by dispersion polymerization
WANG ZhanLi;LIU LianYing;DENG JianPing;MA YuHong;YANG WanTai
Journal of Beijing University of Chemical Technology ›› 2007, Vol. 34 ›› Issue (1) : 39-43.
Monodispersed cationic microspheres of polystyrene prepared by dispersion polymerization
WANG ZhanLi;LIU LianYing;DENG JianPing;MA YuHong;YANG WanTai
Cationic microspheres of polystyrene were prepared through dispersion polymerization in methanol with [2-(methacryloyloxy)ethyl] trimethylammonium chloride (DMC) as polymeric stabilizer and AIBN as initiator. The polymerization behavior and effects of varying the concentration of stabilizer, monomer and initiator onparticle size and size distribution were studied. By means of SEM, it was shownthat monodispersed microspheres of polystyrene with particle size in the range of 0.98~2.78μm could be obtained.
[1]KAWAGUCHI H. Functional polymer microspheres[J]. Prog Polym Sci,2000, 25: 1171-1210.
[2]曹同玉,刘庆普,胡金生. 聚合物乳液合成原理性能及应用[M]. 北京:化学工业出版社,2002:304-310,474-477.
[3]OHSHIMA H, KONDO T. Approximate analytic expression for the electrophoretic mobility of a spherical colloidal particle[J]. J Colloid Interface Sci, 1989, 130: 281-282.
[4]MIRABALLESMARTINEZ I. Synthesis of latex particles with surface amino groups[J]. J Polym Sci, Part A: Polym Chem, 2000, 38: 4230-4237.
[5]XU Zushun, ZHANG Jinzhi, CHENG Shiyuan. Study actuality of cationic polymerization[J]. Journal of Functional Polymers, 1995, 8(4): 512-519.
[6]DALES M J. Crosslinked gel ion exchange resin beads characterized by strain birefringence patterns: US, 4192921[P]. 1980-03-11.
[7]GOODWIN J W, HEARN J, HO C C, et al. Preparation and characterization of polymer lattices formed in the absence of surface active agents[J]. Br Polym J, 1973, 5: 347-362.
[8]LIU Zuifang, XIAO Huining, WISEMAN N. Emulsifier-free emulsion copolymerization of styrene with quaternary ammonium cationic monomers[J]. J Appl PolymSci, 2000, 76: 1129-1140.
[9]SONG B K, CHO M S. Dispersion polymerization of acrylamide with quaternary ammonium cationic comonomer in aqueous solution[J]. J Appl Polym Sci, 2002, 87: 1101-1108.
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