Use γ-aminopropyltriethyoxyl silane to prepare poly-γ-aminopropyl polyhedral oligomeric silsesquioxane by hydrolyzation and condensation has been reported in this paper. The process of hydrolyzation and condensation reaction has been discussed in detail. The structures of products were characterized by FTIR, XRD, NMR. The configuration of polyhedral oligomeric silsesquioxane was proved in the products. The reaction mechanism was deduced.
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
References
[1] Baney R H, Itoh M, Sakakibara A ,et al . Silsesquioxanes, Chem Rev[J].1995 ,95 (5): 1409～1430.
[2]Fu B X, YangL, SomaniRH, Crystallization Studies of Iocatictic Polypropylene Containing Nanostructured Polyhedral Oligomeric Silsesquioxane Molecules under Quiescent and Shear Conditions J. polym. Sci[J]. Part B: Polym Physics, 2001, 39(22): 2727～2739.
[3]BrounJF, VogtLH, EustanceJW, et al. Doublechainpolymersof phenysilsesquioxan,
J. Amer. Chem. Soc[J]. 1960 (82): 6194
[4]袁长友，胡春野，笼形八聚(五甲基二硅氧) 倍半硅氧烷，有机硅材料[J].2001，15(2)：1～4.
[5]陆方，严宝珍，胡高飞，笼形倍半硅氧烷NMR的研究，波谱学杂志[J]. 2004, 21(1)：57-60
[6]Guizhi Li, Lichang Wang, Hanli Ni, et al.Polyhedral Oligomeric Silsesquioxane (POSS)Polymers and Copolymers: A Review，Journal of Inorganic and Organometallic Polymers[J]. 2001(11):123-154
{{custom_fnGroup.title_en}}
Footnotes
{{custom_fn.content}}
PDF(394 KB)
