A novel LCuX [L=Et2NCH2CH2NC(Me)CHC(Me)O, X=Cl] compound was coordinated by the β-diketiminato ligand and plenty of drying CuCl2, and characterized by elemental analysis, NMR and infrared spectra techniques. Such β-dike timinato ligand was prepared in a toluene solvent in light of the theory of co-boiling of oil and water. The geometries of the ligand and the complex were optimi zed in terms of the DFT method, a Local Spin Density Approximation Calculations. The IR spectra were also calculated and compared with the experimental data. And the results are reasonable.
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References
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