Synthesis, characterization and structure determination of a novel LCuX compounds coordinated by the β-diketiminato ligand [L=Et2NCH2CH2NC(Me)CHC(Me)O, X=Cl]

ZHAO Qing;CAO Wei-liang;YANG Zuo-ying;ZHANG Jing-chang*

Journal of Beijing University of Chemical Technology ›› 2005, Vol. 32 ›› Issue (6) : 68-71.

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Journal of Beijing University of Chemical Technology ›› 2005, Vol. 32 ›› Issue (6) : 68-71.
研究论文

Synthesis, characterization and structure determination of a novel LCuX compounds coordinated by the β-diketiminato ligand [L=Et2NCH2CH2NC(Me)CHC(Me)O, X=Cl]

  • ZHAO Qing;CAO Wei-liang;YANG Zuo-ying;ZHANG Jing-chang*
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Abstract

A novel LCuX [L=Et2NCH2CH2NC(Me)CHC(Me)O, X=Cl] compound was coordinated by the β-diketiminato ligand and plenty of drying CuCl2, and characterized by elemental analysis, NMR and infrared spectra techniques. Such β-dike timinato ligand was prepared in a toluene solvent in light of the theory of co-boiling of oil and water. The geometries of the ligand and the complex were optimi zed in terms of the DFT method, a Local Spin Density Approximation Calculations. The IR spectra were also calculated and compared with the experimental data. And the results are reasonable.

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ZHAO Qing;CAO Wei-liang;YANG Zuo-ying;ZHANG Jing-chang*. Synthesis, characterization and structure determination of a novel LCuX compounds coordinated by the β-diketiminato ligand [L=Et2NCH2CH2NC(Me)CHC(Me)O, X=Cl][J]. Journal of Beijing University of Chemical Technology, 2005, 32(6): 68-71

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