Ferrocenium tetrafluoroborate salt for curing epoxide under visible lights

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Journal of Beijing University of Chemical Technology ›› 2005, Vol. 32 ›› Issue (4) : 84-90.

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WANG Tao;ZHANG Li-xin;HUANG Yu-li

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Ferrocenium tetrafluoroborate salt([CpFeCp]BF₄), as a cationic photoinitiator, was found to be able to initiate the curing of cycloaliphatic epoxide under visible lights. It is found by photolysis the absorption at 620nm is effective for initiating the curing of epoxide. The initiating activity and the affecting factors were investigated. The results show that the curing rate of the system of cycloaliphatic epoxide ERL-4221/[CpFeCp]BF₄ increases with the increase in the light intensity and the curing temperature.

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WANG Tao;ZHANG Li-xin;HUANG Yu-li. Ferrocenium tetrafluoroborate salt for curing epoxide under visible lights[J]. Journal of Beijing University of Chemical Technology, 2005, 32(4): 84-90

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[1 ] 　施文芳,刘和文,王方景. 环氧树脂的紫外光引发阳离子/ 自由基固化[J ] . 应用化学,1997 ,14 (1) :53 - 60
[2 ] 　Fouassier J P , Allonas X , Burget D. Photopolymerization reactions under visible lights : principle ,mechanisms and examples of applications [J ] . Progress in Organic Coatings , 2003 ,47 :16 - 23
[3 ] 　Crivello J V. The discovery and development of onium salt cationic photoinitiator [ J ] . J Polym Sci : Part A :Polymer Chemistry , 1999 , 37 : 4241 - 4254
[4 ] 　Crivello J V , Sangermano M. Visible and long-wavelength photoinitiated cationic polymerization[J ] . J Polym Sci : Part A : Polymer Chemistry , 2001 ,39 :343 - 348
[5 ] 　王涛,黄毓礼,马丽君,等. 二茂铁四氟硼酸盐的阳离子光引发性能的研究[J ] . 感光科学与光化学,2003 ,21 (1) :46 - 52
[6 ] 　Albert GL , Michael W L , Steven B R , et al . Preparation of ferrocenium phosphorus , arsenic , and bismuth halides , the structure of ferrocenium tetrachlorlbis-muthate[J ] . J Chem Soc Chem Comm , 1976 ,931 - 932
[7 ] 　王涛,杜洪光,黄毓礼. 芳茂铁四氟硼酸盐的制备[J ] .北京化工大学学报,2003 ,30 (1) :83 - 85
[8 ] 　王涛,王志华,唐钦民,等. UV 光谱研究[ Cp-Fe-Cp ]BF4 和[Cp-Fe-Naph ]BF4 的光解动力学及机理[J ] . 光谱学与光谱分析,2002 ,22 (6) : 920 - 925

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Received	Revised	Published
2004-09-21	1900-01-01	2005-08-10
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2005-08-10

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