BOPP膜表面化学键组装制备多层膜

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北京化工大学学报（自然科学版） ›› 2006, Vol. 33 ›› Issue (4) : 30-33.

研究论文

BOPP膜表面化学键组装制备多层膜

赵洪池;刘莲英;杨万泰*&#;

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Fabrication of a multilayer construction on a bi-oriented polypropylene (BOPP) surface via chemical bonding assembly

ZHAO Hong-chi; LIU Lian-ying;YANG Wan-tai

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摘要

本文首先通过紫外光照射将半频哪醇自由基偶合到双向拉伸聚丙烯（BOPP）膜表面，然后利用该偶合基团上的羟基与对苯二甲酰氯（TPC）和双酚A（BPA）进行交替反复的逐步缩合反应，制备了以共价键结合的多层组装膜。采用紫外（UV）、红外光谱（ATR-FTIR）跟踪和证实了组装膜的形成，并且膜的组装比较规则。

Abstract

A multilayer construction has been fabricated on a bi-oriented polypropylene (BOPP) surface via a chemical bonding assembly process. The first step in the fabrication process involves the introduction of semipinacol groups onto the BOPP surface by hydrogen abstraction by benzophenone (BP) and coupling of the resultant semipinacol radicals with the surface under UV irradiation. The second step involves a condensation reaction between the hydroxyl group of the semipinacol moiety and terephthaloyl chloride (TPC) followed by successive condensation reactions of bis-phenol A (BPA) and TPC. The formation of the assembled film can be conveniently monitored by UV spectroscopy and ATR-FTIR spectroscopy.

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赵洪池;刘莲英;杨万泰*
. BOPP膜表面化学键组装制备多层膜[J]. 北京化工大学学报（自然科学版）, 2006, 33(4): 30-33

ZHAO Hong-chi; LIU Lian-ying;YANG Wan-tai. Fabrication of a multilayer construction on a bi-oriented polypropylene (BOPP) surface via chemical bonding assembly[J]. Journal of Beijing University of Chemical Technology, 2006, 33(4): 30-33

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收稿日期	修回日期	出版日期
2006-03-14	1900-01-01	2006-08-10
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2006-08-10

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