新型有机光致变色材料螺噁嗪的合成

严宝珍1); 吕 强2)

北京化工大学学报(自然科学版) ›› 2001, Vol. 28 ›› Issue (4) : 56-59.

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北京化工大学学报(自然科学版) ›› 2001, Vol. 28 ›› Issue (4) : 56-59.
研究论文

新型有机光致变色材料螺噁嗪的合成

  • 严宝珍 吕 强
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Synthesis of novel organic photochromic spirooxazine compounds

  • YAN Bao-zhen1) ; LUQiang2)
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摘要

文中以1,3,3-三甲基-2-甲叉吲哚啉和亚硝基酚为原料合成了四种螺噁嗪光致变色化合物,分别是:(1)化合物A:1,3,3-三甲基螺吲哚啉-2,3′-[3H]萘并[2,12b][1,4]嗪;(2)化合物B:1,3,3-三甲基-6′-哌啶-螺吲哚啉-2,3′-[3H]萘并[2,12b][1,4]嗪;(3)化合物C:1,3,3-三甲基-6′-二甲胺基-螺吲哚啉-2,3′-[3H]苯并[2,12b][1,4]嗪;(4)化合物D:1,3,3-三甲基-6′-二乙胺基-螺吲哚啉-2,3′-[3H]苯并[2,12b][1,4]嗪。对各化合物进行了一些光致变色试验,并对所产生的现象进行了简要的讨论。

Abstract

Four photochromic compounds were synthesized using 1 ,3 ,3-trimethyl-2-methylene-indoline and nitrosophenol. These compounds are : (1) compound A : 1 ,3 ,3-trimethylspiroindoline-2 ,3′- [ 3H] naphtho [ 2 ,12b] [1 ,4 ]oxazine ; (2) compound B : 1 ,3 ,3-t rimethyl-6′- spiroindoline-2 ,3′- [ 3H] naphtho [ 2 ,12b ] [ 1 ,4 ]oxazine ; (3) compound C: 1 ,3 ,3-t rimethyl-6′- trimethylamino-spiroindoline-2 ,3′- [3H] benzo [2 ,12b ] [1 ,4 ]oxazine ; (4) compound D : 1 ,3 ,3-t rimethyl-6′- diethylamino-spiroindoline-2 , 3′- [ 3H ] benzo [ 2 , 12b ] [ 1 , 4 ]oxazine. The differences in photochromic behaviors of these compounds in different solvent s were compared and discussed.

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导出引用
严宝珍1); 吕 强2). 新型有机光致变色材料螺噁嗪的合成[J]. 北京化工大学学报(自然科学版), 2001, 28(4): 56-59
YAN Bao-zhen1) ; LUQiang2). Synthesis of novel organic photochromic spirooxazine compounds[J]. Journal of Beijing University of Chemical Technology, 2001, 28(4): 56-59

参考文献

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[2 ]  Shinnichi Yamamoto , Takashi Taniguchi. Spirooxazinebeing photochromic compounds having excellent resistance to fatigue and providing choice of various hues. J P :WO 89 07 104 ,1989
[3 ]  Wang Mingsing , Andrew T H. Synthesis and photochromic properties of novel spirooxazine. Polymer Bulletin ,1994 , 33 : 275
[4 ]  Rickwood M , Marsden S D. Red coloring photochromic 6′2 substitrted spiroindolinonaphth [ 2 , 12b ] [ 1 , 4 ] oxazines. Mol Cryst Liq Cryst Sci Technol Sect A ,1994 ,17 : 246
[5 ]  Paul Rys , Ruth Weber , Wu Qinglan. Light-induced change of the molecular charge in a spironaphthoxazine compound. Can J Chem , 1993 , 71(11) : 1828
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