高选择性SAPO-34分子筛的合成及催化性能

韩殷哲1,2;左胜利1*;刘建军1

北京化工大学学报(自然科学版) ›› 2013, Vol. 40 ›› Issue (2) : 20-24.

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北京化工大学学报(自然科学版) ›› 2013, Vol. 40 ›› Issue (2) : 20-24.
化学与化学工程

高选择性SAPO-34分子筛的合成及催化性能

  • 韩殷哲,;左胜利*;刘建军
作者信息 +

Synthesis and catalytic performance of high selectivity of SAPO-34 molecular sieve

  • HAN UnChol1, 2;ZUO ShengLi1;LIU JianJun1
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文章历史 +

摘要

以磷酸铝为铝源和磷源用水热合成法制备了具有CHA骨架结构的SAPO-34分子筛,采用XRD、BET、NH3-TPD和SEM等手段对分子筛进行了表征。以甲醇裂解制取低碳烯烃(MTO)为模型反应,采用固定床反应装置,对制备的分子筛进行了催化性能评价。结果表明,合成的分子筛具有SAPO-34结构,酸性较强,在MTO反应中几乎只有乙烯生成,对乙烯的选择性达到90%以上,再生性能(热稳定性)较好,与按照传统方法合成的SAPO-34分子筛相比,催化性能更好。

Abstract

A SAPO-34 molecular sieve with the CHA framework was synthesized by a hydrothermal method using aluminum phosphate as the source of aluminum and phosphorus, and characterized by XRD, BET, NH3-TPD and SEM techniques. The catalytic performance of the molecular sieve was experimentally evaluated by taking methanol-to-olefins (MTO) as a model reaction in a fixed-bed reactor. The results showed that the molecular sieve only generated ethylene in the MTO reaction and the selectivity to ethylene was over 90%. Furthermore, the molecular sieve was found to have good regenerativity (or thermostability). Compared with SAPO-34 molecular sieves prepared by conventional methods, our product has a better catalytic performance, and thus it has good prospects for industrial application.

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导出引用
韩殷哲1,2;左胜利1*;刘建军1. 高选择性SAPO-34分子筛的合成及催化性能[J]. 北京化工大学学报(自然科学版), 2013, 40(2): 20-24
HAN UnChol1, 2;ZUO ShengLi1;LIU JianJun1
.
Synthesis and catalytic performance of high selectivity of SAPO-34 molecular sieve[J]. Journal of Beijing University of Chemical Technology, 2013, 40(2): 20-24

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