电泳沉积法制备氧化铝陶瓷膜的研究

陈晓晓;魏刚;张元晶;付国柱;乔宁*

北京化工大学学报(自然科学版) ›› 2011, Vol. 38 ›› Issue (5) : 69-74.

PDF(2882 KB)
欢迎访问北京化工大学学报(自然科学版),今天是 2025年4月5日 星期六
Email Alert  RSS
PDF(2882 KB)
北京化工大学学报(自然科学版) ›› 2011, Vol. 38 ›› Issue (5) : 69-74.
材料科学与工程

电泳沉积法制备氧化铝陶瓷膜的研究

  • 陈晓晓;魏刚;张元晶;付国柱;乔宁*
作者信息 +

Preparation of alumina ceramic membranes by electrophoresis

  • CHEN XiaoXiao;WEI Gang;ZHANG YuanJing;FU GuoZhu;QIAO Ning

Author information +
文章历史 +

摘要

以工业级陶瓷片为支撑体,氧化铝溶胶为电泳液,采用电泳沉积的方法制备了氧化铝陶瓷膜。当在30 V的电压条件下电泳3 min,经沉积-干燥-烧结工艺,反复进行3次后,即可得到氧化铝纳滤膜。采用SEM和液-液排除法等手段对纳滤膜进行表征,结果表明,膜厚在50 μm左右,孔隙率为31.51%,平均孔径为3.1 nm,孔径分布为2.88~5.76 nm。性能测试表明,氧化铝纳滤膜对无机污染物和有机污染物均有强的截留作用,且性能较稳定。

Abstract

Alumina ceramic membranes have been prepared by electrophoresis using an industrial ceramic as the electrophoretic matrix and alumina sol as the electrophoretic liquid. A nanofiltration membrane was prepared using the electrophoretic process and a coating-drying-sintering process repeated three times. The optimum electrophoresis time was found to be 3min with a voltage of 30 V. The Al2O3 ceramic membrane obtained under these experimental conditions was characterized by SEM and liquid-liquid displacement methods. A ceramic membrane with a thickness of 50 μm had a porosity ratio of 31.51%, a pore size of 3.1 nm and a pore size distribution of 2.88 nm to 5.76 nm. Performance tests showed that the membrane had strong interception effects on both inorganic pollutants and organic pollutants.

引用本文

导出引用
陈晓晓;魏刚;张元晶;付国柱;乔宁*. 电泳沉积法制备氧化铝陶瓷膜的研究[J]. 北京化工大学学报(自然科学版), 2011, 38(5): 69-74

CHEN XiaoXiao;WEI Gang;ZHANG YuanJing;FU GuoZhu;QIAO Ning

.
Preparation of alumina ceramic membranes by electrophoresis [J]. Journal of Beijing University of Chemical Technology, 2011, 38(5): 69-74

参考文献

[1] 宋玉军, 刘福安, 杨勇, 等. 纳滤膜的制备及应用技术研究进展[J]. 化工科技, 1999, 7(3): 1-7. 
Song Y J, Liu F A, Yang Y, et al. Review on the preparation and application of nanofiltration membrane[J]. Sci-Tech in Chemical Industry, 1999, 7(3): 1-7. (in Chinese)
[2] 李亚军, 隋贤栋, 黄肖容. 无机纳滤膜的研究进展[J]. 材料导报, 2003, 17: 30-32.
Li Y J, Sui X D, Huang X R. Research progresses on inorganic nanofiltration membranes[J]. Journal of Materials Review, 2003, 17: 30-32. (in Chinese)
[3] Ryan W, Massoud E. Electrophoretic deposition could speed up ceramic casting[J]. International Ceramic Review, 1979(2): 117-119. 
[4] Harbach F, Weiler L. Reliable ceramic components from colloidal suspensions[J]. Berichte der Deutschen Keramischen Gesellschaft, 1990, 67: 130-135. 
[5] 范晓丹, 梁辉, 徐明霞, 等. 微孔Al2O3膜电泳沉积的研究[J]. 天津大学学报, 2000, 33(5) : 663-664. 
Fan X D, Liang H, Xu M X, et al. Study on electrophoretic deposition processing of Al2O3 microporous membranes[J]. Journal of Tianjin University, 2000, 33(5): 663-664. (in Chinese)
[6] Egben J, Koro S W J. Ceramic membrane characterization via the bubble point technique[J]. Journal of Mem brane Science, 1997, 124(2): 149-159. 
[7] 国家环保局. 水和废水监测分析方法[M]. 3版. 北京: 科学出版社, 1989: 354-356.
The State Environmental Protection Administration. Monitoring analysis method of water and wastewater[M]. 3rd Edition. Beijing: Science Press, 1989: 354-356. (in Chinese)
[8] 赵文涛, 史景利, 郭全贵, 等. 石墨基体电泳沉积法制备SiC涂层[J]. 宇航材料工艺, 2008 (4): 51-54. 
Zhao W T, Shi J L, Guo Q G, et al. SiC coating by electrophoretic deposition on graphite substrate[J]. Journal of Space Material Technology, 2008 (4): 51-54. (in Chinese)
[9]李树尘, 陈长勇, 许基清. 材料工艺学[M]. 北京: 化学工业出版社, 2000: 113. 
Li S C, Chen C Y, Xu J Q. Materials technology[M]. Beijing: Chemical Industry Press, 2000: 113. (in Chinese)
PDF(2882 KB)

2955

Accesses

0

Citation

Detail

段落导航
相关文章

/