
丙烯酸甲酯对羧基氯丁胶乳聚合体系的影响
Effect of added methyl acrylate on the polymerization of carboxylic chloroprene emulsion
The influence of added methyl acrylate (MA) on the emulsion copolymerization of methacrylic acid (MAA) and chloroprene in the presence of polyvinyl alcohol as a protective colloid was investigated. It was found that the latex viscosity decreased significantly from 1.36Pa·s to 0.10Pa·s after addition of 30% MA and the particle size of the latex decreased with increasing MA content. A dispersion polymerization mechanism has been proposed in order to account for the effects of added MA on the latex viscosity and particle size.
[1]于敏, 李广宇. SBS型胶粘剂与性能改进[J]. 化学与粘合, 2002, 9(1): 24-25.[2]李广宇, 于敏, 李子东. 氯丁橡胶胶粘剂的发展方向[J]. 粘接, 2003,
24(6): 24-26.
[3]陈静, 杨枫. 氯丁橡胶胶粘剂的研究及应用进展[J]. 化学与粘合,2000(2): 79-82.[4]FITZGERALD K D. Stable polychloroprene latex: US, 4128514[P]. 1978-10-05[2005-04-29]. http:∥patents.uspto.gov.
[5]BRIZZOLARA, HONSBERG, WOLFGANG. Polychloroprenepolyvinyl alcohol latex: US, 4141875[P]. 1979-02-27[2005-04-29]. http:∥patents.uspto.gov.
[6]SATOH, MIKITOSHI, KOGA, et al. Method of producing a polychlororpre
ne latex: US, 5661205[P].1997-08-26[2005-04-29]. http:∥patents.uspto.gov.
[7]NOLTE, WILFRIED, ESSEER,et al. Process for the production of poly
chloroprene lattices rich in solid matter: US, 4338238[P].1982-07-06[2005 -04-29]. http:∥patents.uspto.gov.
[8]BIBEAU A A. Polymerization process for producing polychloroprene particles: US, 4035564[P].1977-07-12[2005-04-29]. http:∥patents.uspto.gov.
[9]VOSS, GARY D, SMITH. High adhesion of a variety of rubber compounds to fabric using a single resorcinol-formaldehyde latex composition: US, 6054527[P]. 2000-04-25[2005-04-29]. http:∥patents.uspto.gov.
[10]PEREIRA, MARIA A, IYER, et al. Waterbased contact cement:
US, 5476896[P]. 1995-12-19[2005-04-29]. http:∥patents.uspto.gov.
[11]CHISTELL A L. Polychloroprene adhesive latex composition: US, RE366
18 [P]. 2000-03-14[2005-04-29]. http:∥patents.uspto.gov.
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