TiO2对共沉淀法制备Pd/Al2O3-TiO2催化活性的影响

刘 慷1;金兑源2 ;张立群1

北京化工大学学报(自然科学版) ›› 2005, Vol. 32 ›› Issue (1) : 47-50.

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北京化工大学学报(自然科学版) ›› 2005, Vol. 32 ›› Issue (1) : 47-50.
研究论文

TiO2对共沉淀法制备Pd/Al2O3-TiO2催化活性的影响

  • 刘 慷;金兑源 ;张立群
作者信息 +

Effect of TiO2 on Al2O3 supported Pd catalyst preparedby coprecipitation

  • LIU Kang1;KIM Ta-won2 ;ZHANG Li-qun1
Author information +
文章历史 +

摘要

文中采用共沉淀法制备了混合载体质量分数为1%的Pd/Al2O3-TiO2催化剂,借助XRD和XPS对样品进行了表征,结果表明:混合载体Al2O3-TiO2为无定形结构;TiO2降低了Pd和Al2O3的相互作用能力。将样品应用于C3H6选择催化还原NO反应,以NO转化率为活性评价指标对催化剂的活性进行了对比,发现TiO2的含量对催化剂活性有显著影响:随着TiO2质量分数从0增加至50%,催化剂活性迅速增加;TiO2质量分数超过50%,催化剂活性增加趋势变缓。

Abstract

A series of 1% Pd/Al2O3-TiO2 catalysts were prepared by coprecipitation method.XRD and XPS were used for the catalysts characterization. The characterization results showed that the structure of Al2O3-TiO2 was amorphous. TiO2 reduced the combination energy between Pd and Al2O3. Samples were used for selective catalytic reduction of NO with C3H6 and the conversion of NO was taken as the factor for characterizing the catalytic activity. It is found that the content of TiO2 has a prominent effect on the catalytic activity. As the content of TiO2 is less than 50%, the catalytic activity is enhanced quickly. The growth of the catalytic activity takes on gradual tendency when the contents of TiO2 are beyond 50 percent.

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导出引用
刘 慷1;金兑源2 ;张立群1. TiO2对共沉淀法制备Pd/Al2O3-TiO2催化活性的影响[J]. 北京化工大学学报(自然科学版), 2005, 32(1): 47-50
LIU Kang1;KIM Ta-won2 ;ZHANG Li-qun1. Effect of TiO2 on Al2O3 supported Pd catalyst preparedby coprecipitation[J]. Journal of Beijing University of Chemical Technology, 2005, 32(1): 47-50

参考文献

[1 ]  Hu C Z , Wan Y K, Lui J Detting , et al . Design of a novel Pd three2way catalyst : integration of catalytic functions in three dimensions[J ] . Cat today , 1996 ,30 (1- 3) : 83 - 89
[2 ]  Kumthekar M W , Ozkan U S. Nitric oxide reduction with methane over Pd/ TiO2 catalysts [ J ] . J Cat ,1997 ,171 (1) : 45 - 53
[3 ]  Ogata A , Obuchi A , Mizuno K, et al . Selective reduction of nitric oxide with propene over platinum2group based catalysts : Studies of surface species and catalytic activity[J ] . Apply Cat B , 1995 ,6 (4) : 311 -323
[4 ]  Mitome J , Karakas G, Byran K A , et al . Effect of H2O and SO2 on the activity of Pd/ TiO2 catalysts in catalytic reduction of NO with methane in the presence of oxygen[J ] . Cat Today , 1998 ,42 (1) : 3 - 10
[5 ]  Luiza Ana , Salgado S M , Passos F B. NO reduction by ethanol on Pd and Mo catalysts supported on HZSM25[J ] . Cat Today , 2003 ,85 (1) : 23 - 29
[6 ]  Rodenas E , Yamaguchi T , Hideshi H , et al . Surface and catalytic properties of TiO2-Al2O3 [J ] . J Cat , 1981 ,69 (3) : 434 - 444
[7 ]  Ramiroz J , Ramirez L , Cedeno L , et al . Titania-alumina mixed oxides as supports for molybdenum hydrotreating catalysts [J ] . Appl Cat A , 1993 , 93 (2) :163 - 180
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