新型三维无机-有机杂化材料的水热法合成

张丽娟;王崇臣;

北京化工大学学报(自然科学版) ›› 2004, Vol. 31 ›› Issue (6) : 70-73.

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北京化工大学学报(自然科学版) ›› 2004, Vol. 31 ›› Issue (6) : 70-73.
研究论文

新型三维无机-有机杂化材料的水热法合成

  • 张丽娟;王崇臣;
作者信息 +

Hydrothermal synthesis of novel three-dimensional organic-inorganic hybrid materials

  • Zhang Li-juan;Wang Chong-chen;
Author information +
文章历史 +

摘要

文中通过溶剂热法合成无机有机杂化材料Co2(bpp)4V4O12·4H2O(bpp为1,3-联(4-吡啶基)丙烷),对影响溶剂热反应的主要因素如反应物摩尔比、反应温度、pH值等进行系统研究,确定了合成这种新型化合物的最佳条件。同时还比较说明刚性4,4'-联吡啶和柔性1,2-二-(4吡啶基)乙烷和1,3-二(4-吡啶基)丙烷对无机骨架的影响和Co2(bpp)4V4O12·4H2O晶体结构的新颖之处。

Abstract

In this paper, the reaction conditions such as the mole ratio, reaction temperature and the pH value were systematically investigated through the hydrothermal synthesis of Co2(bpp)4V4O12·4H2O (bpp=1,3-bis(4-pyridyl)propane), and the optimum conditions of this reaction were determinated. At the same time, the influences of the rigid 4,4'-bipyridine and the flexible 1,2-bis(4-pyridyl)ethane and 1,3-bis(4-pyridyl)propane on the crystal structures were explored.

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导出引用
张丽娟;王崇臣;. 新型三维无机-有机杂化材料的水热法合成 [J]. 北京化工大学学报(自然科学版), 2004, 31(6): 70-73
Zhang Li-juan;Wang Chong-chen;. Hydrothermal synthesis of novel three-dimensional organic-inorganic hybrid materials[J]. Journal of Beijing University of Chemical Technology, 2004, 31(6): 70-73

参考文献

[1] Devi R N, Zubieta J. Synthesis and characterization of three novel inorganic/organic hybrid materials based on polyoxomolybdate cluster: An investigation into the structural consequences of steric effect of the organoimine ligands[J]. Inorganica chimica acta, 2002, 332: 72-78
[2] Devi R N, Burkholder E, Zubieta J. Hydrothermal synthesis of polyoxotungstate clusters,surface-modified with M(Ⅱ)-organonitrogen subunits[J]. Inorganica chimica acta, 2003, 348: 150-156
[3] Rarig R S Jr, Zubieta J. Hydrothermal synthesis and structural characterization of an organic-inorganic hybrid materials(H2tptz)2[δ-Mo8O26]·2H2O(tptz=2,4,6-tripyridyltriazine) [J]. Inorganica chimica acta, 2001,312: 188-196
[4] Xu L, Li M, Wang E. Nanosized inorganic-organic hybrid between polyoxometalate anion [PW9Co3O37]9-and р-phenylenediamine[J]. Materials Letters, 2002, 54:303-308
[5] Hegetschweiler K, Finn R C, Zubieta J. Surface complexation of [Nb6O19]8-with NiⅡ: solvothermal syntheis and X-ray structural characterization of the two novel heterometallic Ni-Nb-polyoxometalates [ J]. Inorganica Chimica Acta, 2002, 337: 39-47
[6] Rarig R S Jr, Bewley L, Zubieta J. Hydrothermal synthesis and characterization of a novel bimetallic polyoxocation, [Cu6(dtbbpy)6Mo7O26]2+(dtbbpy=4,4’ditert-butyl-2,2’-bipyridine)[J]. Inorganic Chemistry Commu-
nications, 2003(6): 539-542
[7] 陈春雪,郭洪猷.配位聚合物的溶剂热法合成[J].北京化工大学学报,2004,31(2):69-72
[8] Carlucci L, Gianfranco C. 1-,2-,and 3-dimentional polymeric frames in the coordination chemistry of AgBF4with pyrazine: The first example of three interpentrating 3-dimentional triconnected nets[J]. Am Chem Soc, 1995,
117:4562-4569
[9] Jensen P, Batten S R. Synthesis, structural isomerism,and magnetism of extended framework compounds of type [Cu(dca)2(pyz)]n, where dca= dicyanamide (N(CN)2) and pyz=prazine[J]. Journal of Solid State Chemistry,
1995, 145: 387-393
[10] 李增和,银陈,郭洪猷.无机-有机杂化化合物[Co(μ2-bpy)V2O6] (bpy =4,4’-联吡啶)的水热合成和晶体结构[J].物理化学学报, 2003, 19: 1133-1137
[11] 银陈.含氧无机-有机杂化材料的合成,结构及性能的研究[D]. [学位论文].北京:北京化工大学,2003
[12] Carlucci L, Ciani G, Proserpio D M. New polymeric networks from the self-assembly of silver(Ⅰ) salts and the flexible ligand 1,3-bis(4-pyridyl)propane (bpp): A systematic investigation of the effects of the counterions and a survey of the coordination polymers based on bpp[J]. Cryst Eng Comm, 2002,4: 121-129

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